Diastereoselective synthesis of O symmetric heterometallic cubic cages.
نویسندگان
چکیده
Enantiopure chiral cubic cages have been diastereoselectively synthesized for the first time. Chiral amines lead to the isolation of O symmetric homochiral cubic cages, while an achiral amine gives a racemic mixture. CD enhancement is observed as a result of configuration rigidity.
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عنوان ژورنال:
- Chemical communications
دوره 51 18 شماره
صفحات -
تاریخ انتشار 2015